Construction and crystal structures of pillar[5]arene-based bis-[1]rotaxanes via quadruple hydrogen bonding of ureidopyrimidinone

نویسندگان

چکیده

A series of the functionalised pillar[5]arene ureidopyrimidinone derivatives were successfully synthesised by condensation reaction mono-amido-functionalised pillar[5]arenes with 2-(1-Imidazolylcarbonylamino)-6-methyl-4-pyrimidinone in dry chloroform. 1H NMR, 2D NOESY spectra and single crystal structure clearly indicated that novel [1]rotaxanes formed insertion longer alkylene chain into cavities pillar[5]arenes. On other hand, ureidopyrimidinone-functionalised tend to form dimer chloroform solid state through self-complementary quadruple hydrogen bonding ureidopyrimidinone.

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ژورنال

عنوان ژورنال: Supramolecular Chemistry

سال: 2021

ISSN: ['1029-0478', '1061-0278', '1026-7816']

DOI: https://doi.org/10.1080/10610278.2022.2142122